Bottom sediments can be significant sinks for a variety of heavy metals and metalloids coming from various anthropogenic sources. When these sediments are dredged and disposed of to land, drying and oxidation can lead to several changes in their physico-chemical properties, such as redox potential and pH, and hence to changes in metal mobility. Therefore, this work was conducted to study the adsorptiondesorption behaviour of one selected heavy metal - copper - in three bottom sediment samples before and after drying. Moreover, possible geochemical associations of As, Cd, Co, Cu, Hg, Ni, Pb and Zn in the airdried sediments were studied using a modified BCR sequential extraction protocol. Generally, redox state of the sediments changed from the highly anoxic to oxic and adsorption of Cu2+ decreased when the originally anoxic sediments were dried. On the other hand, the enhanced release of Cu2+ was observed from the air-dried sediments. The adsorption-desorption data showed that the changes in metal leachability occurred between originally anoxic and air dried sediments. In terms of water and soil pollution by Cu and likely other heavy metals, it appears that the dredged, air-dried sediments could represent somewhat greater contamination risks when compared with the originally anoxic sediments. Using the sequential extraction data, leaching potential of heavy metals and arsenic in the air-dried sediments was possible to evaluate with Cd, Co, Zn as the most mobile heavy metals, followed by Cu, Ni, As, Pb and Hg, respectively. and Dnové sedimenty sú významnými adsorbentmi celej rady ťažkých kovov a polokovov, ktoré pochádzajú z rôznych antropogénnych zdrojov. Po vyťažení týchto sedimentov z vodných nádrží na zemský povrch prechádzajú procesmi sušenia a oxidácie, ktoré menia niektoré ich vlastnosti, ako oxidačno-redukčný potenciál a pH, a teda môžu ovplyvňovať pohyblivosť potenciálne toxických kovov prítomných v sedimentoch. Z tohto dôvodu cieľom práce bolo štúdium adsorpcie a desorpcie jedného vybraného ťažkého kovu - medi - v troch vzorkách dnových sedimentov pred vysušením a po ňom. Okrem toho sme pomocou modifikovanej BCR metódy sekvenčnej extrakcie študovali možné geochemické interakcie ťažkých kovov (Cd, Co, Cu, Hg, Ni, Pb, Zn) a arzénu s jednotlivými zložkami dnových sedimentov. Ako ukázali experimentálne výsledky, počas sušenia sa zmenili redukčné podmienky v sedimentoch na oxidačné a adsorpčná kapacita vysušených sedimentov vzhľadom k Cu2+ bola výrazne nižšia ako u pôvodných sedimentov. Na druhej strane, množstvo uvoľneného Cu2+ z vysušených sedimentov bolo vyššie ako z pôvodných sedimentov. Uvedené zistenia teda poukazujú na zmenu v správaní a pohyblivosti potenciálne toxických prvkov medzi pôvodnými, redukčnými sedimentmi a tými, ktoré prešli procesom sušenia a oxidácie. Z hľadiska znečistenia prírodných vôd a pôd meďou a pravdepodobne aj ďalšími ťažkými kovmi sa zdá, že v porovnaní s pôvodnými kontaminovanými sedimentmi vyťažené a na vzduchu vysušené sedimenty môžu predstavovať vyššie riziko pre životné prostredie. Podľa výsledkov sekvenčnej extrakcie sa ukázalo, že Cd, Co a Zn sú po vysušení v skúmaných sedimentoch veľmi mobilnými prvkami, pričom pohyblivosť ostatných prvkov klesá v poradí Cu > Ni > As > Pb >> Hg.
The presence of gravel in soils modifies the porosity, pore connectivity and pore size distribution in the soil matrix as well as the soil matrix-gravel interfaces. The aim of the present study is to investigate the effect of relative volume of gravel in samples with gravel mass fractions of 5,10, 20 wt% and varying bulk densities (1.3, 1.45, 1.55, 1.60, 1.65 g cm–3) on (i) total porosity, field capacity, plant available water holding capacity, (ii) pore size distribution and (iii) thermal capacity of repacked sandy and silty soils. The focus of the study was to determine if laboratory measured soil water retention curves considering (i), (ii), and (iii) can be predicted by a gravel-based weighting factor, Rv, considering comprehensive significance tests. The sand-gravel mixtures show a decrease in the volume fractions of macropores and wide cores pores with an increase in the gravel contents, while the silt-gravel mixtures show an opposite trend. The root mean square errors (RMSE) between measured and fitted volumetric water contents, θ, between 0.006 and 0.0352 and between 0.002 and 0.004 for Rv-weighted volumetric water contents indicate that the van Genuchten-based Peters-Durner- Iden (PDI) model is appropriate for fitting. The soil water retention curves with mass gravel contents of up to 10 wt% for silt and 20 wt% for sand can be well predicted by weighting factors (relative volume of rock fragments) in the range between 0.045 and 0.058 for silt, and between 0.112 and 0.119 for sand. The results also indicate a decrease in the Rv-weighted saturated, cvsat, and dry, cvdry, thermal capacity with an increase in the gravel contents for both soils. Further investigations are needed to examine if and whether measured sand- and silt-gravel mixtures with mass gravel contents below 10 % or rather 20 % can be predicted with a weighting factor.
The interception process in subalpine Norway spruce stands plays an important role in the distribution of throughfall. The natural mountain spruce forest where our measurements of throughfall and gross precipitation were carried out, is located on the tree line at an elevation of 1,420 m a.s.l. in the Western Tatra Mountains (Slovakia, Central Europe). This paper presents an evaluation of the interception process in a natural mature spruce stand during the growing season from May to October in 2018–2020. We also analyzed the daily precipitation events within each growing season and assigned to them individual synoptic types. The amount and distribution of precipitation during the growing season plays an important role in the precipitation-interception process, which confirming the evaluation of individual synoptic situations. During the monitored growing seasons, precipitation was normal (2018), sub-normal (2019) and above-normal (2020) in comparison with long-term precipitation (1988–2017). We recorded the highest precipitation in the normal and above-normal precipitation years during the north-eastern cyclonic synoptic situation (NEc). During these two periods, interception showed the lowest values in the dripping zone at the crown periphery, while in the precipitation sub-normal period (2019), the lowest interception was reached by the canopy gap. In the central crown zone near the stem, interception reached the highest value in each growing season. In the evaluated vegetation periods, interception reached values in the range of 19.6–24.1% of gross precipitation total in the canopy gap, 8.3–22.2% in the dripping zone at the crown periphery and 45.7–51.6% in the central crown zone near the stem. These regimes are expected to change in the Western Tatra Mts., as they have been affected by windstorms and insect outbreaks in recent decades. Under disturbance regimes, changes in interception as well as vegetation, at least for some period of time, are unavoidable.
Microplastics (particles of plastics <5 mm) affect the physical, biological and hydrological properties of agricultural soil, as well as crop growth. We investigated the effect of the addition of three microplastics (high-density polyethylene (HDPE), polyvinyl chloride (PVC), and polystyrene (PS)) at a concentration of 5% (w/w) to a silty loam soil on selected soil properties and growth of radish (Raphanus sativus L. var. sativus). Changes in the soil properties and radish growth in three microplastic treatments were compared with the control. Soil properties (bulk density, hydraulic conductivity, sorptivity, water repellency) were estimated for each treatment at the beginning and at the end of the radish growing period (GP). The bulk density was significantly lower in the HDPE and PVC treatments compared to the control within the measurement at the beginning of the GP and in all microplastic treatments compared to the control at the end of the GP. The values of hydraulic conductivity and water sorptivity did not show significant differences between any treatments within the measurement at the beginning of GP, but they were significantly higher in the HDPE treatment compared to the control at the end of the GP. The growth of radish was characterized by the plant biomass and effective quantum yield of Photosystem II (Y (II)). We did not find a statistically significant difference in the total biomass of radish between any of the experimental treatments, maybe due to used concentration of microplastics. The mean value of Y (II) was significantly higher in all microplastic treatments compared to control only within the last measurement at the end of the GP. A statistically significant change of Y(II) in all microplastic treatments may indicate functional shift in soil properties; however, the measured values of the soil characteristics have not shown the significant changes (except for the bulk density values in all microplastic treatments and hydraulic conductivity together with sorptivity in HDPE treatment within the measurement at the end of GP).
The Bavarian Danube River has experienced numerous large flood events in recent years which make flood management an urgent matter. The propagation of flood waves along the river is heavily influenced by controlled and natural flood retention. Over the past centuries, natural flood retention areas were lost due to river training, and the hydraulic characteristics of the channel-flood plain system were modified. The purpose of this paper is to understand the effect of river training on the flood retention characteristics along the Bavarian Danube. Systematic two-dimensional hydrodynamic modelling shows that extreme floods are attenuated more strongly in the present state of the channel-flood plain system than they were historically. This is because the retention areas are filled later during the event, so the attenuation effect is much larger for the same magnitude of the retention volume. Natural flood retention is therefore not an effective management option for reducing extreme floods on the Bavarian Danube. Controlled flood retention measures provide a higher efficiency regarding peak attenuation to retention volume ratio. On the other hand, the delay of flood peaks due to natural retention may be beneficial for the superposition of the flood waves with contributions from downstream tributaries.
Sand burial is a ubiquitous disturbance that influences the ecological and hydrological properties of moss crusts in many sandy desert areas. There is little available information regarding the effect of sand burial on the water repellency (WR) of moss crusts in desert areas. Therefore, this study evaluated the effects of sand burial (sand depths of 0 (control), 0.5, 1, 2, 4 and 10 mm) followed by three simulated precipitation regimes (through applying 4 and 6 mm, 2 and 3 mm, and 1 and 1.5 mm of distilled water at 8-day intervals in spring and autumn, respectively) on the WR of a widespread moss crust dominated by Bryum argenteum Hedw. in a revegetated area of the Tengger Desert, China. The results showed moss crust WR remained subcritical during the whole experiment, and that it considerably decreased immediately after sand burial, even though the values of WR were significantly higher in autumn than those in spring under the same treatment (p < 0.05). Furthermore, the depth threshold (TD) values for sand burials that reduced WR to zero were 1 and 2 mm in spring and autumn, respectively. After a recovery period of nearly one-season (72 days), the WR of the moss crust significantly increased (p < 0.05). In addition, sand burial had two separate effects on moss crust WR. Specifically, shallower sand burial (burial depth less than 0.5 mm) increased moss crust WR, whereas deeper sand burial (burial depth exceeds 0.5 mm) decreased it. The TD values also significantly increased to 2 and 4 mm in spring and autumn, respectively. These findings about the effects of sand burial on moss crust WR provide additional information that can be used to better understand the influence of sand burial on moss crust colonization and maintenance in arid sandburial- stressed ecosystems, and to help explain why there are some contrasting viewpoints on biocrust WR.
Hillslope hydrology in agricultural landscapes is complex due to a variety of hydropedological processes and field management possibilities. The aim was to test if there are any differences in soil properties and water regime along the hillslope and to compare vineyard rows (vine) with inter-rows (grass) area for those properties. The study determined that there are significant differences in the contents of soil particle fractions, pH, and humus content along the slope (P < 0.0001), with lower confidence level in bulk density (P < 0.05). Differences between row and inter-row space were significant for the pH, humus, and silt content, but for sand and clay content, and bulk density differences were not determined. The study determined differences in soil water content among five slope positions (P < 0.0001), and between row and inter-row vineyard space (all with P < 0.05). Where in the upper slope positions (e. g., P1) soil water content was higher than on lower slope positions. Higher soil water content was observed at higher slope positions, associated with clay content. However, it can be concluded that the retention of moisture on the slope is more influenced by local-scale soil properties (primarily soil texture) and variability of the crop (row/inter-row) than the position on the slope.
An open channel flume with a central 180-degree bend with a rigid bed is designed to obtain a better understanding of the complex flow pattern around a T-shaped spur dike located in a sharp bend. The 3-dimensional velocities are measured by using an acoustic Doppler velocimetry under clear-water conditions. This study's primary objective is to compare variations of the mean flow pattern along a 180-degree bend with a variety of T-shaped spur dike lengths. In order to do so, parameters such as streamlines, the maximum velocity distribution, and the secondary flow strength under the influence of three T-shaped spur dike lengths will be analyzed and then compared with the case where no spur dikes are implemented. The results show that with the spur dike placed at the bend apex, the mean secondary flow strength at that range increases by approximately 2.5 times. In addition, a 67% increase in the length of the wing and web of the spur dike leads to a 27% growth in the mean secondary flow strength along the bend.
Accurate estimates of infiltration and groundwater recharge are critical for many hydrologic, agricultural and environmental applications. Anticipated climate change in many regions of the world, especially in tropical areas, is expected to increase the frequency of high-intensity, short-duration precipitation events, which in turn will affect the groundwater recharge rate. Estimates of recharge are often obtained using monthly or even annually averaged meteorological time series data. In this study we employed the HYDRUS-1D software package to assess the sensitivity of groundwater recharge calculations to using meteorological time series of different temporal resolutions (i.e., hourly, daily, weekly, monthly and yearly averaged precipitation and potential evaporation rates). Calculations were applied to three sites in Brazil having different climatological conditions: a tropical savanna (the Cerrado), a humid subtropical area (the temperate southern part of Brazil), and a very wet tropical area (Amazonia). To simplify our current analysis, we did not consider any land use effects by ignoring root water uptake. Temporal averaging of meteorological data was found to lead to significant bias in predictions of groundwater recharge, with much greater estimated recharge rates in case of very uneven temporal rainfall distributions during the year involving distinct wet and dry seasons. For example, at the Cerrado site, using daily averaged data produced recharge rates of up to 9 times greater than using yearly averaged data. In all cases, an increase in the time of averaging of meteorological data led to lower estimates of groundwater recharge, especially at sites having coarse-textured soils. Our results show that temporal averaging limits the ability of simulations to predict deep penetration of moisture in response to precipitation, so that water remains in the upper part of the vadose zone subject to upward flow and evaporation.
The paper deals with the effect of the parameters of aqueous slurries of particulate matter on the functional relationship between the specific energy and the flow rate of hydrodynamic dredge pumps. The empirical conversion equations available from literature are reviewed. The methods of converting the pump characteristics at clear water to those which apply for slurries have been incorporated into a straightforward, user-friendly computer program which can be run on a PC. The program may be adopted in the design of hydro-transportation systems involving hydrodynamic dredge pumps. The program computes the specific pump energy as a function of flow rate at given rotary speed, for specific operating conditions of the pump, i.e., for specific parameters of the slurry.The paper deals with the effect of the parameters of aqueous slurries of particulate matter on the functional relationship between the specific energy and the flow rate of hydrodynamic dredge pumps. The empirical conversion equations available from literature are reviewed. The methods of converting the pump characteristics at clear water to those which apply for slurries have been incorporated into a straightforward, user-friendly computer program which can be run on a PC. The program may be adopted in the design of hydro-transportation systems involving hydrodynamic dredge pumps. The program computes the specific pump energy as a function of flow rate at given rotary speed, for specific operating conditions of the pump, i.e., for specific parameters of the slurry. and Článek pojednává o vlivu parametrů hydrosměsi písku na funkční vztah měrná energie - průtok hydrodynamických bagrovacích čerpadel. Uvádí přehled empirických přepočtových vztahů v dostupných literárních podkladech. Metody přepočtu charakteristik čerpadla z čisté vody na hydrosměs byly zapracovány do uživatelsky jednoduchého výpočtového programu pro osobní počítač. Program lze využít při návrhu hydrodopravních systémů s hydrodynamickými bagrovacími čerpadly. Výstupem programu jsou závislosti měrné energie čerpadla na průtoku při daných otáčkách pro konkrétní podmínky provozu čerpadla, resp. pro konkrétní parametry suspenze.