Metalloporphyrins serve important roles in biology and as components in emerging technological assemblies for energy conversion. In this report, we describe the synthesis and characterization of a novel cobalt(II) 5,10,15,20-tetrakis
(3-fluorophenyl)porphyrin bearing a 4-vinylphenyl surface attachment group at a beta position on the macrocycle. Electrochemical measurements show the 3-fluorophenyl groups at the meso positions of the porphyrin perturb the reduction potentials of the complex to more positive values as compared to
non-fluorinated analogs, thus allowing access to reduced cobalt porphyrin species at significantly less negative applied bias potentials. The complex, cobalt(II) 5,10,15,20-tetrakis(3-fluorophenyl)-2-(4-vinylphenyl)porphyrin, is abbreviated in this article as Gov-1 in honor of Govindjee for his pioneering investigations in the role of fluorine as a promoter of novel
protein-substrate interactions and the inspirational role he continues to have in encouraging young investigators in the areas of natural and artificial photosynthesis., D. Khusnutdinova, M. Flores, A. M. Beiler, G. F. Moore., and Obsahuje bibliografické odkazy
Cuckoos parasitize many rare and inconspicuous host species but avoid other common and conspicuous ones. In this article, results of a study that solved this long-standing ecological conundrum are described. I use this work to illustrate va - rious weaknesses of typical ecological studies (sample size, data representativeness, reification) and give suggestions for a better research practice in the future. and Jiří Klimeš, Ivan Literák.
In our previous work we established a T7 polymerase-driven Tetracycline-inducible protein expression system in Leishmania mexicana (Biagi, 1953). We used this system to analyse gene expression profiles during development of L. mexicana in procyclic and metacyclic promastigotes and amastigotes. The transcription of the gene of interest and the T7 polymerase genes was significantly reduced upon cell differentiation. This regulation is not locus-specific. It depends on untranslated regions flanking open reading frames of the genes analysed. In this paper, we report that the previously established conventional inducible protein expression system may not be suitable for studies on differentiation of species of Leishmania Ross, 1903 and protein expression systems might have certain limitations., Aygul Ishemgulova, Natalya Kraeva, Drahomíra Faktorová, Lucie Podešvová, Julius Lukeš, Vyacheslav Yurchenko., and Obsahuje bibliografii
Čeleď kabarovitých představuje pro většinu lidí nejméně zajímavou čeleď kopytníků. Zahrnuje 7 málo známých druhů žijících ve východní Asii (od východního Afghánistánu přes Himálaj, Tibet a Čínu po střední a východní Sibiř). Tento článek obsahuje hlavní charakteristiky jednotlivých druhů včetně jejich fylogeneze a shrnuje dosavadní znalostí o životě kabarů. Vzhledem k tomu, že kabaři představují významný zdroj pro tradiční čínskou medicínu, stávají se v poslední době i jednou z nejvíce ohrožených čeledí kopytníků., The family Moschidae involves 7 species of musk deer, inhabiting forests and mountains of East Asia (from Afghanistan to the Himalayas, from Tibet and China to Siberia). This article summarizes current knowledge of individual species characteristics, including their phylogeny and natural history. Since these animals are a valuable source for the traditional Chinese medicine, they are the most endangered ungulate species in the world., and Jan Pluháček.
There are two genera of Eublepharid geckos described in Africa – Hemitheconyx and Holodactylus. The morphological differences of both species of genus Holodactylus – H. africanus and H. cornii, living in the Horn of Africa, are described. Although the basic information on ethology is also discussed, it is obvious that there are still many secrets concerning these interesting lizards. and Pavel Konečný, Tomáš Mazuch.
Štěnice domácí (Cimex lectularius) svým parazitickým způsobem života dohání k šílenství miliony lidí po celém světě. Přes všechny negativní aspekty jsou štěnice velmi zajímavým objektem studia, zejména pak po stránce cytogenetiky. Vyznačují se nezvyklými holokinetickými chromozomy a mnoha dalšími zvláštními modifikacemi průběhu buněčného dělení. Třešničkou na dortu je ohromná variabilita v počtu pohlavních chromozomů., The Bed Bug (Cimex lectularius) with its parasitic way of life is known around the whole world. However, in spite of all the negatives, Bed Bugs are very interesting objects to study, particularly in the field of cytogenetic science. They are characterised by unusual holokinetic chromosomes and many more interesting modifications of cell division. The icing on the cake is the huge variability in the number of sex chromosomes., and David Sadílek, Martin Forman, Jitka Vilímová.
Malajsie jako tropická země patří mezi 12 biologicky nejbohatších a druhově nejrůznorodějších států světa. Její přírodní bohatství tak představuje jedno z vhodných míst k prvnímu seznámení se s faunou a flórou tropických lesů. Jedním z největších přírodních lákadel kontinentální Malajsie je světově nejstarší tropický nížinný les národního parku Taman Negara, jehož druhová diverzita obojživelníků a plazů je předmětem tohoto článku., Malaysia is one of the twelve biologically richest and the most species diverse states in the world. One of the biggest natural attractions of continental Malaysia is the world’s oldest lowland tropical forest in the Taman Negara National Park. The species diversity of amphibians and reptiles of the Taman Negara are presented., and Daniel Jablonski.
To explore the debated phylogenetic relationship of two Hesperiidae subfamilies, Pyrginae and Eudaminae, and contribute to the understanding of the evolution of mitogenomic architecture in butterflies, we sequenced the complete mitogenome of Tagiades vajuna. The mitogenome is a typical circular duplex molecule of 15,359 bp. Apart from the standard 22 tRNAs, it has a tandem duplication of trnS(AGN) and trnE, which is unique in lepidopteran insects. Comparison with Ctenoptilum vasava indicates that the trnS1 duplication is not an ancestral state shared with other species of Tagiadini. Independent origin of the trnS1 duplications was further confirmed by the reconstruction of the ancestral character state based on the topology of the phylogram. Furthermore, comparative analysis of mitogenomes with and without tRNA duplications indicates that tRNA duplication does not alter the codon usage pattern. The mitogenome has negative AT- and GC-skews, and it is highly A+T-biased (79.7%). The AT-rich (or control) region (283 bp) contains "ATAGA" and "ATTTA" motifs. Regarding the phylogenetic analysis, we found that removal of the third codon position (3CP) from datasets used for the mitochondrial phylogenomics of Hesperiidae is likely to produce results that are more consistent: Pyrginae were rendered paraphyletic by Eudaminae in both analyses of the dataset from which the 3CP was removed (13 PCGs + all RNAs), but inclusion of the 3CP resulted in a destabilized topology, resulting in both monophyly and polyphyly. We conclude that even shallow-phylogenies of insects should pay close attention to compositional and mutational biases in mitogenomes., Fang-Fang Liu, Yi-Ping Li, Ivan Jakovlić, Xiang-Qun Yuan., and Obsahuje bibliografii