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132. Determination of chlorite, muscovite, albite and quartz in claystones and clay shales by infrared spectroscopy and partial least-squares regression
- Creator:
- Ritz, Michal, Lenka Vaculíková, Eva Plevová, Dalibor Matýsek, and Mališ, Jiří
- Format:
- print, bez média, and svazek
- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, infračervená spektroskopie, chemometrie, křemen, infrared spectroscopy, chemometrics, quartz, claystone and clay shale, chlorite, muscovite, albite, 7, and 551
- Language:
- English
- Description:
- The objective of this work is the chemometric quantification of minerals in rocks. A chemometric method was developed for the determination of chlorite, muscovite, albite and quartz in claystones and clay shales using infrared spectroscopy. Bromide pellets and diffuse reflectance were used to measure the infrared spectra; principa l component analysis and partial least-squares regression were used as chemometric methods. Spectral regions (4000-3000 cm-1 and 1300-400 cm-1) containing important spectral information were chosen by principal compone nt analysis. The calibration models were created by a partial least-squares regression. The mean relative error and relative standard deviation were calculated for the assessment of accuracy and reproducibility. The value of the mean relative error was about 10 % for most of the calibration models. The value of the relative standard deviation ranged from 1.1 to 3.0 % for most calibration models based on diffuse reflectance spectra and from 4.0 to 9.2 % for most calibration models based on spectra obtained with bromide pellets., Michal Ritz, Lenka Vaculíková, Eva Plevová, Dalibor Matýsek and Jiří Mališ., and Obsahuje bibliografické odkazy
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
133. Determination of efficiency in course of guarantee measurments
- Creator:
- Zdeněk Kadlec, Bohumír Čech, and Jan Matoušek
- Format:
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- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, kotle, spalování, boilers, combustion, efficiency, head losses, 7, and 551
- Language:
- English
- Description:
- It is the objective of this thesis to take into account thermal balance of circulating fluidised bed combustors (CFBC), aiming at efficiency assessment, as regards standards, CSN 07 0302, and DIN 1942. It points to differences between calculations along these two different standards, concerning the solution of problems like different comparative temperatures, to which the calculation of physical losses is related to, varying calculation of mean thermal capacity, or problem of electrical motors input. This article is based on the project GA 617 50 11 solving - "Combine combustion of coal and biomass in fluid boilers"., Zdeněk Kadlec, Bohumir Čech and Jan Matoušek., and Obsahuje bibliografii
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
134. Determination of emission and oxidation factors in monitoring CO2 emissions for emission trading scheme
- Creator:
- Pavel Fott, Kolář, František, and Vácha, Dušan
- Format:
- print, bez média, and svazek
- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, skleníkové plyny, emisní práva, greenhouse gases, emissions trading, emission and oxidation factors, CO2 monitoring, 7, and 551
- Language:
- English
- Description:
- EU Emission Trading Scheme, which is applied in EU Member States to decrease CO 2 emissions, requires accurate, reliable, comparable and transparent methodology for monitoring, reporting and verification of emissions. Existing Monitoring and Reporting Guidelines provides operators only with general and undetailed instructions. This paper should provide the plant operators with guidance for a better understanding, interpretation and mastering of the methods of monitoring and reporting CO2 emissions for the purposes of emission trading. This paper is focused on experimental determination of emission and oxidation factors of solid fuels and on calculation of emission factors of gaseous fuels from their composition., Pavel Fott, František Kolář and Dušan Vácha., and Obsahuje bibliografické odkazy
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
135. Determination of intermediate orbit and position of glonass satellites based on the generalized problem of two fixed centers
- Creator:
- Władysław Góral and Skorupa, Bogdan
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- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, geofyzika, geophysics, GLONASS, orbit determination, problem of two fixed centers, 7, and 551
- Language:
- English
- Description:
- The mathematical model and algorithms for calculating the position of GLONASS satellites by means of their broadcast ephemeris is presented in the paper. The algorithms are based on the generalized problem of two fixed centers. One of the advantages of the analytical solution obtained from the generalized problem of two fixed centers is the fact that it embraces perturbations of all orders, from the second and also part ly from the third zonal harmonics (Aksenov, 1969). GLONASS broadcast ephemeris - provided every 30 minutes - contain satellite position and velocities in the Earth fixed coordinate system PZ-90.02 (ICD, 2008), and acceleration due to luni-solar attraction. The GLONASS Interface Control Document recommends that a fourth order Runge-Kutta integration algorithm shall be applied. In the Department of Geomatics (AGH UST) a computer program has been established for fitting position and velocity of GLONASS satellites using their broadcast ephemeris. Intermediate GLONASS satellite orbits are calculated consider ing also the second and third zonal harmonics in the gravitational potential of the Earth. In this paper results of the analytical integration of the equation of the motion of the GLONASS satellites compared to the numerical solution are provided., Władysław Góral and Bogdan Skorupa., and Obsahuje bibliografické odkazy
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
136. Determination of minerals in coal by methods based on the recalculation of the bulk chemical analyses
- Creator:
- Ritz, Michal and Zdeněk Klika
- Format:
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- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, uhlí, chemická analýza, coal, chemical analysis, phase analysis, 7, and 551
- Language:
- English
- Description:
- Chemical Quantitative Phase Analysis (CQPA) suggested originally for magmatic rocks (Klika et al., 1986) now is tested for the quantitative mineral determination of coal. This method is based on the optimization procedure. For the evaluation of mineral contents, 5 coal samples were selected and the following analytical data were determined: a) chemical analyses (XRF, titrimetric and gravimetric analytical methods), b) qualitative mineral composition (the X-ray powder diffraction, SEM-EDX and image analyses), c) crystallochemical formulae of minerals. The calculated percentages of minerals obtained by CQPA were compared with calculated percentages of minerals obtained by Raask´s method. Simple statistical evaluation showed that calculation of minerals by CQPA program delivers considerable improvement of results., Michal Ritz and Zdeněk Klika., and Obsahuje bibliografii
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
137. Determination of near-surface apparent resistivity by means of high frequency mutual impedance measurements
- Creator:
- Beziuk, Grzegorz and Mydlikowski, Remigiusz
- Format:
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- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, geofyzika, geophysics, geophysical method, loop antennas, mutual impedance, apparent resistivity, 7, and 551
- Language:
- English
- Description:
- A method of determination the apparent resistyvity of the ground’s near-surface la yers from measurements of the mutual impedance of a loop antenna system operating at a high frequency is presented. An analysis of the sensitivity of mutual impedance to variation in the parameters of conducting half space at different frequencies had been carried out. Additionally influence of displacement current on measured mutual impedance values was discussed. A frequency of measuring system was selected in order to obtain a high sensitivity of the measuring system to detection inhomogeneities characterised by small dimensions and low apparent resistyvity contrast. The measuring system and the method of interpreting measurement results were described. The results of field measurements were presented., Grzegorz Beziuk and Remigiusz Mydlikowski., and Obsahuje bibliografické odkazy
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
138. Determination of quasigeoid in local network using modern astrogeodetic technologies
- Creator:
- Volařík, Tomáš, Radovan Machotka, Kuruc, Michal, Puchrik, Lukáš, and Jurčík, Josef
- Format:
- print, bez média, and svazek
- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, geodezie, geodesy, astrogeodetic vertical deflections, astronomical levelling, quasigeoid heights, Mobile Automated Astronomical System (MAAS), 7, and 551
- Language:
- English
- Description:
- This study shows the test usage of Mobile Automated Astronomical System No. 1 (M AAS-1) in a local network with an are a of approximately 50 km sq. The network has been built-up especially for experimental purposes to compare the local quasigeoid model determined by three different methods, namely GNSS-levelling, astronomical levelling and gravimetry. The network consists of 34 core points where the astronomic and geodetic coordinates have been measured. Subsequently, the measured data have been processed to obtain vertical deflections and to determine the quasigeoid heights by astronomical levelling. Afterwards, the quasigeoid model has been independently determined also using gravimetric measurements and by the method of GNSS-levelling. In this paper the results of th e comparison of quasigeoid models are being presented. The overall agreement of independently determin ed quasigeoids is on the level of 3 mm. After an overall accuracy evaluation of resulting quasigeoid model authors discuss the benef its of astronomical measur ements using MAAS-1., Tomáš Volařík, Radovan Machotka, Michal Kuruc, Lukáš Puchrik and Josef Jurčík., and Obsahuje bibliografické odkazy
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public
139. Determination of the horizontal deformation factor for mineral and fluidized deposits exploitation
- Creator:
- Sroka, Anton, Misa, Rafał, and Tajdus, Krzysztof
- Format:
- print, bez média, and svazek
- Type:
- model:article and TEXT
- Subject:
- geodynamika, geomechanika, geofyzika, geologie, těžba nerostných surovin, geodynamics, geomechanics, geophysics, geology, horizontal deformation, horizontal displacement, mining operation, Avershin’s hypothesis, 7, and 551
- Language:
- English
- Description:
- In this article, the authors use the existing theoretical foundations and partial solutions to provide a general formula, which can be used to determine the value of horizontal deformation factor B for various applications of the Knothe theory. This applies to the calculation of surface deformation not only in the case of hard coal mining, but also in the case of salt mining by borehole. Convergence resulted from mining may cause deformations of caverns used to store liquid and gaseous fuels or the deformations related to the fluidized bed extraction. The calculations for the new analytical model are presented in the examples of the Etzel cavern (Germany) and the Upper Silesian Coal Basin (Poland). and Sroka Anton, Misa Rafał, Tajdus Krzysztof.
- Rights:
- http://creativecommons.org/publicdomain/mark/1.0/ and policy:public
140. Determination of the not-modelled short periodic variations in the GPS permanent site's positions
- Creator:
- Bogusz, Janusz and Ján Hefty
- Format:
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- Type:
- article, články, model:article, and TEXT
- Subject:
- Geologie. Meteorologie. Klimatologie, GPS (navigační systém), GPS (navigation system), short-time solutions, periodic signals, ASG-EUPOS, 7, and 551
- Language:
- English
- Description:
- This paper describes the researches upon the precise short-time GPS solutions made in the Centre of Applied Geomatics, Military University of Technology. The data from ASG-EUPOS (Polish Active Geodetic Network) was processed using Bernese 5.0 software and EPN (EUREF Permanent Network) standards and models. In this study, the adopted 3-hour observation window is shifted every hour obtaining geocentric coordinates in ITRF2005 reference frame. The adjusted network consisted of over 130 stations from Poland and the neighbouring countries, the period covered observations collected from 8.06.2008 to 18.06.2010. These two years of observations allowed to examine short-period oscillations which we found as closely related to the tidal (dynamic) frequencies. The analysis of the residua from IERS2003 tidal model was performed using least squares method with the Eterna software upon the idea of Chojnicki. It confirmed existence of the significant energy in the frequencies corresponding to S1, K1 and K2. The effects in S1 frequency reflect thermal influences, but the reasons of K1 and K2 existence could be both: dynamic (liquid core resonance and non-linearity of K1 are very difficult for modelling as well as the annual modulation of S1) or artificial (GPS satellites’ orbiting period, dynamic changes of satellites’ constellation and network geometry, multipath, residual tropospheric and ionospheric errors etc.). Since the phase of K1 for all 130 sites is very inconsistent the local effects could be also taken into account as one of the possible reasons. The paper describes the idea of the data processing and analysis, presents the results of vertical (Up component) oscillations in main tidal frequency bands, but also includes the discussion on the possible explanation of existence of short period oscillations in GPS precise solutions., Janusz Bogusz and Jan Hefty., and Obsahuje bibliografii
- Rights:
- http://creativecommons.org/licenses/by-nc-sa/4.0/ and policy:public