During the last decade, biochar has captured the attention of agriculturalists worldwide due to its positive effect on the environment. To verify the biochar effects on organic carbon content, soil sorption, and soil physical properties under the mild climate of Central Europe, we established a field experiment. This was carried out on a silty loam Haplic Luvisol at the Malanta experimental site of the Slovak Agricultural University in Nitra with five treatments: Control (biochar 0 t ha–1, nitrogen 0 kg ha–1); B10 (biochar 10 t ha–1, nitrogen 0 kg ha–1); B20 (biochar 20 t ha–1, nitrogen 0 kg ha–1); B10+N (biochar 10 t ha–1, nitrogen 160 kg ha–1) and B20+N (biochar 20 t ha–1, nitrogen 160 kg ha–1). Applied biochar increased total and available soil water content in all fertilized treatments. Based on the results from the spring soil sampling (porosity and water retention curves), we found a statistically significant increase in the soil water content for all fertilized treatments. Furthermore, biochar (with or without N fertilization) significantly decreased hydrolytic acidity and increased total organic carbon. After biochar amendment, the soil sorption complex became fully saturated mainly by the basic cations. Statistically significant linear relationships were observed between the porosity and (A) sum of base cations, (B) cation exchange capacity, (C) base saturation.
Most recent studies on soil water repellency (WR) were limited to the humous topsoil or to shallow subsoil layers slightly below the main root zone to approximately 0.5 m depth. Hence, the main objective of the present study was to investigate the wettability pattern of a forest soil including the deeper subsoil. The selected site was a 100 years old beech forest on a well-drained sandy Cambisol in northern Germany which showed moderate to partly extended acidification. Results obtained from three sampling transects (3 m length, 2 m depth; sampling grid 8 × 8 samples per transect; minimum distance of sampling locations to nearest tree about 0.5 m) show that contact angles (CA) were always in the subcritical WR range (0° < CA < 90°). Significant impact of the tree distance on WR was not observed for any of the transects. A prominent feature of two transects was the minimum WR level (CA < 10°) for samples with soil organic carbon (SOC) contents around 0.25-0.4%. For the topsoils it was observed that CA increased with SOC content from that minimum to a maximum CA of 60-75° for transects 1 and 2 with mean pH values < 3.5. For transect 3 with slightly higher average pH close to 4.0, average CA of samples were always < 10° and showed no trend to increase with increasing SOC content or other soil parameters like N content or C/N ratio. Subsoil samples, however, behave differently with respect to SOC: for these samples, generally low in SOC, the CA increase with decreasing SOC occurred at all transects for approximately 50% of the samples but did not show any clear tendencies with respect to further parameters like texture, pH or N content. We conclude that the SOC content is the most prominent parameter determining wettability, either positively correlated with WR for topsoils or negatively correlated for subsoil samples very low in SOC. We finally conclude for moderately acid beech forest stands that emerging WR starts in the A horizon after reaching a pH lower than 3.5, whereas subsoil WR might appear already at higher pH values. Even SOC contents of ∼0.01-0.02% turned out to be very effective in increasing the CA up to 70°, which points out clearly the importance of small amounts of soil organic matter in affecting subsoil wettability. With respect to site hydrology we conclude that ongoing acidification as well as predicted higher frequencies of extended droughts due to climate change will promote the occurrence of WR with corresponding implications for site and catchment hydrology.
The primary purpose of this work was to assess the persistence of water repellency in the surface horizon of coarse-textured soils under natural Quercus robur ecosystems, and Pinus pinaster and Eucalyptus globulus plantations, in the northwest of the Iberian Peninsula. Water repellency was determined by applying the water drop penetration test (WDPT) to soil samples collected from variable depths (0–40 cm). Measurements were made on field-moist samples obtained at the end of the dry period and on samples dried at 25ºC in the air. All soils exhibited very high (severe to extreme) water repellency in the topmost soil layer (0–5 cm) but no significant differences among the three plant species studied. Extreme persistence was observed down to 20 cm in the soils under eucalyptus and down to 10 cm in those under pine. The soils under oak were those exhibiting the highest variability in water repellency and the greatest decrease in it with increasing depth (especially in relation to soils under eucalyptus).
Water repellency exhibited significant positive correlation with the C content and C/N ratio of the soils. Soil water repellency was similar in the air-dried samples and field-moist samples.
Recent studies show that biochar improves physical properties of soils and contributes to the carbon sequestration. In contrast to most other studies on biochar, the present study comprise a long-term field experiment with a special focus on the simultaneous impact of N-fertilizer to soil structure parameters and content of soil organic carbon (SOC) since SOC has been linked to improved aggregate stability. However, the question remains: how does the content of water-stable aggregates change with the content of organic matter? In this paper we investigate the effects of biochar alone and in a combination with N-fertilizer (i) on the content of water-stable macro- (WSAma) and micro-aggregates (WSAmi) as well as soil structure parameters; and (ii) on the contents of SOC and labile carbon (CL) in water-stable aggregates (WSA).
A field experiment was conducted with different biochar application rates: B0 control (0 t ha–1), B10 (10 t ha–1) and B20 (20 t ha–1) and 0 (no N), 1st and 2nd level of nitrogen fertilization. The doses of level 1 were calculated on required average crop production using the balance method. The level 2 included an application of additional 100% of N in 2014 and additional 50% of N in the years 2015–2016 on silty loam Haplic Luvisol at the study site located at Dolná Malanta (Slovakia). The effects were investigated after the growing season of spring barley, maize and spring wheat in 2014,
2015 and 2016, respectively. The results indicate that the B10N0 treatment significantly decreased the structure vulnerability by 25% compared to B0N0. Overall, the lower level of N combined with lower doses of biochar and the higher level of N showed positive effects on the average contents of higher classes of WSAma and other soil structure parameters. The content of SOC in WSA in all size classes and the content of CL in WSAma 3–1 mm significantly increased after applying 20 t ha–1 of biochar compared to B0N0. In the case of the B20N1 treatment, the content of SOC in WSAma within the size classes >5 mm (8%), 5– 3 mm (19%), 3–2 mm (12%), 2–1 mm (16%), 1–0.5 mm (14%), 0.5–0.25 mm (9%) and WSAmi (12%) was higher than in B0N1. We also observed a considerably higher content of SOC in WSAma 5–0.5 mm and WSAmi with the B10N1 treatment as compared to B0N1. Doses of 20 t biochar ha–1 combined with second level of N fertilization had significant effect on the increase of WSAma and WSAmi compared to the B0N2 treatment. A significant increase of CL in WSA was determined for size classes of 2–0.25 mm and WSAmi in the B20N2 treatment. Our findings showed that biochar might have beneficial effects on soil structure parameters, SOC, CL in WSA and carbon sequestration, depending on the applied amounts of biochar and nitrogen.