Trapped or residual air (or gas) is known to affect the multiphase hydraulic properties of both soils and rocks. Trapped air is known to impact many vadose zone hydrologic applications such as infiltration and flow in the capillary fringe, but is also a major issue affecting recoverable oil reserves. Although many studies have focused on the relationship between porosity and trapped gas saturation (Sgt) in sandstones, far fewer studies have been carried out for carbonate rocks. This work aims to analyze the influence of porous media properties on trapped gas saturation in carbonate rocks. For this we used thirteen Indiana Limestone and Silurian dolomite rock samples from the USA, and several coquinas from the Morro do Chaves formation in Brazil. Pore size distributions were obtained for all samples using Nuclear Magnetic Resonance (NMR), and Mercury Injection Capillary Pressure (MICP) data from three of the samples to determine their pore throat size distributions. Additionally, 3D microtomography (microCT) images were used to quantify macropore profiles and pore connectivities. Results indicate a lower capacity of gas trapping in carbonate rocks in which micro- and mesopores predominate. Results also indicate that in carbonate rocks, pore size exerts a greater influence on the ability of gas trapping compared to pore connectivity, so that rocks with a predominance of macropores have greater capacity for gas trapping, even when the macropores are well interconnected. These findings show that pore characteristics very much affect the processes governing gas trapping in carbonate rocks, and indirectly the multiphase hydraulic properties and recoverable oil reserves of carbonate rock reservoirs.