The presented technological procedure makes it possible to assemble large magnetic blocks from permanent magnets with a high value of maximum energy product in such a way that the individual magnets or magnetic plates are moved toward each other at a controlled speed in the direction perpendicular to the future common contact surface of these magnets, i.e. parallel to the induction lines crossing this contact surface. Unlike in the previously used way of assembling the blocks, it is thus possible to eliminate the influence of partial demagnetization as the blocks are being assembled and consequently to reach higher values of magnetic induction in the air gap of the magnetic circuit. When applying the new method of assembling the blocks for instance in circuits of magnetic filters for the purification of ceramic suspensions, a prerequisite for the further improvement of the technological parameters of filtration is thus created., Václav Žežulka and Pavel Straka., and Obsahuje bibliografické odkazy
On the basis of solid-state aluminium-27 nuclear magnetic resonance measurements a new organo-aluminium complex in coal substance was discovered in the solid extracts obtained both from the Ostrava-Karviná bituminous coal and the North Bohemian Basin brown coal. In the 27 Al MAS NMR spectra it was found that the significant chemical shift at 13.6-14.6 ppm corresponds with that obtained for the aluminium hexaphenoxide complex (14.2 ppm). Therefore, organo-aluminium complex with hexa-coordination to oxygen is present in coal substance., Pavel Straka., and Obsahuje bibliografické odkazy
An occurrence of tetra-coordinated aluminum in altered coal and low temperature coal ashes was investigated. As altered coal a sample from the Lazy mine (Upper Silesian Coal Basin) was tested, further, low-temperature ashes from different coals were prepared and measured. During preparation the selected coal samples were intensively air-oxidized; 27Al MAS NMR spectra of obtained ashes were then acquired and compared against those for initial coals. A reference wood ash and Al standards were used for identification of Al-forms. It was found that chemical shift at 4 ppm with coals corresponds to that for triaquo-hydroxo-diphenoxido-aluminum(III) complex (THDA), further, the shift at 72 ppm with altered coal and resulting ashes agrees with that for Al tetra-coordinated with oxygen. So, in the presence of coal organics the tetra-coordinated Al is formed under low temperature conditions, because during low temperature ashing the THDA complex is transformed to Al tetra-coordinated with oxygen only at 350 °C. A similar process occurred in the case of oxidation of coal substance under low temperature conditions in the nature at temperatures below 150 °C., Pavel Straka., and Obsahuje bibliografii
By use of plastic or rubber admixtures in the stamped charges, it is possible to affect the properties of tar, in contrast to the calorific value of resulting coking gas; further, it was found that the reactivity- and strength parameters of the obtained blast-furnace coke are good or acceptable. Unused plastics or rubber can economize on part of the coal used in a stamped charge. Additions of both light and heavy plastics can be used up to 5 % of a charge weight; in the case of rubber it is not advisable to exceed 2 wt.-% in a charge. In contradiction to the other methods, which process the unused plastics of up to a content of 1 % in a charge, it is possible, in the case of used stamping method, to process even 2 % or more., Pavel Straka., and Obsahuje bibliografické odkazy
On the basis of laboratory and industrial experiments it was found that rubber can be treated by co-gasification with brown coal, namely in the process of the oxygen-steam pressure gasification in a moving bed (Lurgi gasification process). Considering the very low reactivity of the residual char from rubber, the optimal content of the rubber particles in the mixture being gasified should probably not exceed 10 wt.-%, but short-term increases in the proportion of these particles (up to 20 wt.-%) will not cause technological problems or significant economic losses., Pavel Straka, Vlastimil Kříž and Zdeněk Bučko., and Obsahuje bibliografii
The two stage co-pyrolysis method for obtaining of hydrogen is described. In the course of the heating of the mixture of bituminous coal with polyisoprene and styrene-butadiene polymers (co-pyrolysis), a considerable amount of hydrogen and hydrocarbons is released in dependence on the process conditions. The experiments proved that the amount of hydrogen increased already with slightly increased heating rate (5 K min-1 ) in comparison with the amount obtained at a common heating rate (3 K min-1) and, further, with the addition of the second (cracking) stage for further thermal splitting of release d hydrocarbons into hydrogen (and carbon), preferably at a temperature of 1200 ºC., Pavel Straka and Vlastimil Kříž., and Obsahuje bibliografické odkazy
Measurements of the gasification rate of chars from lignite with admixtures by steam or CO2 showed that the admixtures of polymers, celluloses and wood reduce reactivity of resulting chars. The decrease of reactivity significantly manifests itself at both 800 °C and 900 °C. This is caused mainly by lower inner surface area which resists the gasification reactions. This negative phenomenon can be compensated by addition of magnetite, which acts as Fe-catalyst of the reactions of chars with steam as well as CO2 and accelerates the gasification. Through the isoconversional analysis, it was proven that the presence of magnetite significantly lowers the effective activation energy of these reactions, thus accelerating their course. The measurements of the reaction rate showed that it leads to a two- or three-fold acceleration of gasification., Pavel Straka., and Obsahuje bibliografii
Power generation from biomass is a substantial source of ashes, the extent of which depends on the type of biomass fuel and technology of combustion being used. The current study focuses on comparison of ashes with a special emphasis on hazardous organic compounds, particularly the polycyclic aromatic hydrocarbons (PAHs) fraction, present in ash. The reason is that ashes from combustion of wood or straw are considered as fertilizers in agricultural soils. Ash samples were therefore collected from power plants in the Czech Republic coming from combustion of wood chips, sawdust, bark and straw. The organic fraction was separated by extraction, the final determination of PAHs was performed by GC-UV. The total concentration of PAHs was found to be in the range 15-733 μ g/kg. These compounds are formed during the pyrolysis stage of the combustion process by the secondary ar omatization reactions in char at temperatures above 400 °C. The created PAHs are bound in the porous unburned carbon. For a more detailed qualitative analysis of other organic compounds the GC-MS was used. Higher and branched aliphatic hydrocarbons, ketones, amides and phthalates in the sample with the highest unburned carbon content were found., Pavel Straka and Martina Havelcová., and Obsahuje bibliografické odkazy
During separations in both polar and nonpolar stationary phases of gas chromatographic columns, side alkylchains of n-alkylphenols and n-alkylbenzenes become cyclized. In the aromatic-quasi-alicyclic molecules that are thereby formed, the effect of van der Waals forces is thus increased. The increase involves not only intramolecularly but also intermolecularly acting effects and becomes significantly evident when propyl and higher substituents as butyl, pentyl and hexyl constitute the side alkyl chains. As a result, boiling points considerably increase (non-linearly) in the case of n-alkylphenols and n-alkylbenzenes with total number of carbons in the molecule higher than 9. This leads to divergence in the retention characteristics of the above-mentioned compounds, which can be observed in the dependence of relative retention times on the number of carbons. Cyclization of side alkyl chains in a stationary phase is a quite new phenomenon., Pavel Straka, Petr Buryan and Jana Náhunková., and Obsahuje bibliografické odkazy
In the frame of advanced studies of coal structure the temperature conditions of coal origin were investigated through thermal stability of aluminum complexes in coal substance. These compounds were discovered by solid-state nuclear magnetic resonance measurements of 27Al as a part of coal substance closely bonded to organic mass of coal. In obtained spectra, Al-hexaphenoxide and Al-tetrahydroxy-diphenoxide complexes were identified. These complexes were further prepared and their thermal stability tested by thermal analysis method. It was found that a) they can originate under room temperature and atmospheric pressure and b) they are thermally stable only up to approximately 85 or 95 °C. As both Al-hexaphenoxide and Al-tetrahydroxy-diphenoxide complexes are the integrated constituents of coal substance it can be deduced that, in the beginning, coal was formed under very mild thermal conditions. As investigated materials, coals and clays from the Czech basins and gagatite from Poland were measured., Pavel Straka and Jana Náhunková., and Obsahuje bibliografii