In Autumn 2010 a new permanent GPS station started observati ons intended to investigate the episodic displacements o f rocks in the Książ Massif, where the Geodynamic Laboratory (LG) is situated. These investigations are being made for common interpretation with water-tubes and horizontal pendulums tiltmeters registering large (one order of magnitude greate r than the tidal effects) non-periodic geodynamic signals. The studies conducted as up to date excluded instrumental and loading effects as potential reasons of those signals. The construction of water-tube tiltmeters and their measuring principles allowed to state that the strong non-tidal signals have a geodynamic nature. To support investig ation of this problem, different analysis of the GPS data are performed in appropriate scales and applying various processing methods. The applied methods refer to selected reference GPS stations in Poland and their neighbors and are aimed at reduction of disturbance effects of geophysical origin such as tectonic activity, post-glacial rebound, anthropogenic effects, etc., Ryszard Zdunek., and Obsahuje bibliografické odkazy
Physical mass properties of various types of rocks were ascertained, and their relationships are discu ssed in this article. Basedon water permeability and mercury intrusion porosimetry methods, conductivity coefficient, porosity, and pore size distribution were determined. Furthermore, bulk and particle densities of rocks we re determined. All laboratory tests were carried out according to Czech versi on of the Technical specif ication CEN ISO/TS 17892-11:2004. The above-mentioned specification has the status of the Czech standard (ČSN, CEN). Permeability and porosity are in close relation, and it could be assumed that its relationship is linear, i.e., with increasing porosity, permeability increases as well. This relationship is influenced by other rock properties, such as the amount of open and closed pores with in the rock sample, size, and distribution of pores or mineral admixtures. From this point of view, it is necessary to study these physical properties of rocks as well, because this enables an overall analysis of rocks and its possible use for engineering constructions, Jan Šperl and Jiřina Trčková., and Obsahuje bibliografické odkazy
Permeability refers to the ability of coal to transmit gas when a pressure or concentration gradient exists across it. The permeability of coal is dependent upon factors that include effective stress, gas pressure, water content, disturbance associated with drilling and matrix swelling/shrinkage due to adsorption/desorption. A programme of laboratory tests were conducted on coal samples from the Bulli seam for evaluating the permeability and drainability of coal. Two different types of permeability apparatus were used in this study. The methods of permeability testing of coal under different triaxial conditions are discussed. Permeability testing of the Bulli seam coal with N2 is described. The laboratory test results were found to be in agreement with the calculated permeability values, Naj Aziz, Ting Ren, Jan Nemcik and Lei Zhang., and Obsahuje bibliografii
This paper presents preliminary results of the application of Persistent Scatterers Interferometry (PSI) supported with detailed field landslide mapping. The research was focused on the areas located near the towns Rabka Zdroj and Jordanow located in southern-central Poland where detailed landslide mapping campaigns were preformed in the summer of 2009. According to the field experience the average spatial density of landslide occurrence in both areas is up to 3 landslides/sq km. The application of various Synthetic Aperture Radar (SAR) interferometry techniques on the above-mentioned areas was very difficult due to the very rough topography, vegetation and forest cover, and the long season with the snow cover. Following previous successful studies on other rural areas, PSI technique was therefore applied. Field work has been carried out within the frame of a national project launched in 2008 aimed to create a detailed database of all landslides in Poland. The areas where landslide problems are extremely important are the Polish Carpathians. As in previous experiments on a sparse urbanized area we noticed that it is still possible to successfully detect a number of persistent scatterers but, the interpretation of the associated deformation is difficult. However, based on cartographic data collected during the field mapping campaign it is possible to significantly improve analysis and interpretation of PSI results., Zbigniew Perski, Tomasz Wojciechowski and Andrzej Borkowski., and Obsahuje bibliografii
a1_Phyllosilicates are classified into the following groups: 1 - Neutral 1:1 structures: the kaolinite and serpentine group. 2 - Neutral 2:1 structures: the pyrophyllite and talc group. 3 - High-charge 2:1 structures, non-expansible in polar liquids: illite and the dioctahedral and trioctahedral micas, also brittle micas. 4 - Low- to medium-charge 2:1 structures, expansible phyllosilicates in polar liquids: smectites and vermiculites. 5 - Neutral 2:1:1 structures: chlorites. 6 - Neutral to weak-char ge ribbon structures, so-called pseudophyllosilicates or hormites: palygorskite and sepiolite (fibrous crystalline clay minerals ). 7 - Amorphous clay minerals. Order-disorder states, polymorphism, polytypism, and inters tratifications of phyllosilicates are influenced by several factors: 1) a chemical micromilieu acting during the crystallization in any environment, including the space of clay pseudomorphs after original rock-forming silicates or volcanic glasses; 2) the accepted thermal energy; 3) the permeability. The composition and properties of parent rocks and minerals in the weathering crusts, the elevation, and topography of source areas and climatic conditions control the in tensity of weathering, erosion, and there sulting assemblage of phyllosilicates to be transported after erosion. The enormously high accumulation of phyllosilicates in the sedimentary lithosphere is primarily conditioned by their high up to extremely high chemical stability in water-rich environments (expressed by index of corrosion, IKO). Clastic material eroded fro m weathering crusts and transported in rivers contains overwhelming amounts of phyllosilicates inherited from original rocks. In geological literature, the newly formed phyllosilicates crystallizing in weathering crusts including soils as dominating global source of argillaceous lutite accumulations in the sedimentary lithosphere have been overestimate for a long time., a2_The dissolution of silicates in different dense rocks under conditions of weathering and the crystallization of newly formed phyllosilicates has been strongly and for long periods influenced by chemical microenvironments within each clay pseudomorph. Coarser fragments of eroded argillaceous rocks and crystals of phyllosilicates from different bedrocks and soils are very sensitive to impacts and pressure from fragments of co-transported harder and denser rocks and minerals in turbulent fluvial and similar currents. This is the most important mechanical phenomenon supporting the enormous accumulation of lutite rocks rich in phyllosilicates in the sedimentary lithosphere. The summarized new observations and interpre tations are stressed in eleven key poin ts. Erosion and water transportation of detrital material are explained in the terms of hydration, softening, swelling, physical disintegration, grinding, milling, abrasion, delamination, dispersi on, and sorting. The deposition of phyllosilicates in different fluid dynamics of streams is expressed by Re and Fr numbers and explained as unflocculated and floccu lated suspensions. Phyllosilicates an d accompanying detrital minerals in recent marine muds covering vast areas of seas and oceans as well as in lacustrine muds correspond with those transpor ted in fluvial suspensions., Jiří Konta., and Obsahuje bibliografické odkazy
The aim of this paper is to increase the stability of buildings and structures to natural disasters by modifying the Georgian clays into cement concrete filler by creation-using of rehydro-liming pozzolanization technology. The risk of damage-destruction of buildings and structures caused by earthquakes, sea storms, floods, mudflows, has increased in the world. Risks can be prevented by increasing of building and structure stability by reducing the anisotropy of cement concrete strength. To do this: Aqueous aluminosilicate minerals of clays, while dehydrating preserving habitus, are modified into a void containing (...mAl2O3∙nSiO2..) base minerals in which, after mixing in cement concrete while rehydro-liming, Ca(OH)2 is sorbed. The tobermorite, stratlingite, generated in filler, together with cement ettringite form fiber-needle-flaky habit clusters by modifying the structure of cement concrete with 3D self-nano-reinforcement, by reducing the anisotropy of strength - by increasing of stability to loads with variable direction-magnitude. It has been proven that in order to prevent risks of catastrophe, it is possible to use modification of Georgian clays by thermal dehydration in cement concrete technologies, which will create the preconditions for cement concrete pozzolanization by rehydro-liming, so the study of the basics of this process is actual., Rajden Skhvitaridze, Elena Shapakidze, IIoseb Gejadze, Merab Abazadze, Malxaz Turdzeladze, Teimuraz Cheishvili and Akaki Skhvitaridze., and Obsahuje bibliografii
Fluvial archives of the Polish Carpathians bear a record of both climatic and tectonic signatures. The former consist in cyclic development of terrace covers interfingering with and/or overlain by soliluction and slopewash sediments; the latter include disturbances within strath long profiles and differentiated size of erosional downcutting. Valleys of the Outer Carpathians bear five to nine terrace steps of Pleistocene age. Most of these terraces are strath or complex-response ones; the Weichselian and Holocene steps are usually cut-and-fill landforms, except those located in the neotectonically elevated structures characterized by the presence of young straths. Long profiles of individual strath terraces frequently show divergence, convergence, upwarping, downwarping, or faulting that can be indicative of young tectonic control. Moreover, the size and rate of dissection of straths of comparable age are different in different morphotectonic units; a feature pointing to variable pattern of Quaternary uplift. Rates of river downcutting result mainly from climatic changes throughout the glacialinterglacial cycles, but their spatial differentiation appears to be influenced by tectonic factors as well. Examples based on detailed examination of deformed straths and fluvial covers in selected segments of the Polish Carpathian rivers appear to indicate Quaternary reactivation of both normal and thrust bedrock faults. The latter are mostly confined to the eastern portion of the Outer Carpathians. The Early Pleistocene, Holsteinian and Eemian stages of reactivated faulting dominated throughout the study area., Witold Zuchiewicz., and Obsahuje bibliografii
Power generation from biomass is a substantial source of ashes, the extent of which depends on the type of biomass fuel and technology of combustion being used. The current study focuses on comparison of ashes with a special emphasis on hazardous organic compounds, particularly the polycyclic aromatic hydrocarbons (PAHs) fraction, present in ash. The reason is that ashes from combustion of wood or straw are considered as fertilizers in agricultural soils. Ash samples were therefore collected from power plants in the Czech Republic coming from combustion of wood chips, sawdust, bark and straw. The organic fraction was separated by extraction, the final determination of PAHs was performed by GC-UV. The total concentration of PAHs was found to be in the range 15-733 μ g/kg. These compounds are formed during the pyrolysis stage of the combustion process by the secondary ar omatization reactions in char at temperatures above 400 °C. The created PAHs are bound in the porous unburned carbon. For a more detailed qualitative analysis of other organic compounds the GC-MS was used. Higher and branched aliphatic hydrocarbons, ketones, amides and phthalates in the sample with the highest unburned carbon content were found., Pavel Straka and Martina Havelcová., and Obsahuje bibliografické odkazy
Different types of rock crusts and the underlying unweathered sandstone were sampled in the Bohemian Cretaceous Basin, Czech Republic. Structure and mineral composition of the samples were studied using optical microscopy, scanning electron microscopy with EDAX, and X-ray diffraction. Pore parameters were determined using mercury intrusion porosimetry/ helium pycnometry. Principal salts identified in the rock crusts and in the efflorescences are gypsum and alums. Two types of rock crusts were distinguished on morphological basis: 1. patterned rock crusts with a variety of weathering forms (honeycombs, wandkarren), and 2. armoured rock crusts with a relatively smooth, hardened layer. Patterned rock crusts on medium- to coarse-grained quartzose sandstones show an increase in the size of macropores relative to unweathered sandstone, which mostly implies an increase in total effective porosity. This is explained by the subflorescent growth of salt crystals, the force of which leads to the loss of contact among grains, pore widening, and granular disintegration. Armoured rock crusts on fine-grained clayey sandstone show a reduced volume and size of macropores, as these are filled with clay mineral aggregates and gypsum crystals. A prominent increase in the volume of micropores is due to secondary porosity in kaolinite and corrosion of feldspar grains. Insufficient passability of macropores in the armoured layer for pore waters shifts the evaporation front deeper into the rock. This results in contour scaling as the main process of rock-surface degradation, as opposed to granular disintegration on patterned rock crusts., Jiří Adamovič, Radek Mikuláš, Jana Schweigstillová and Vlasta Böhmová., and Obsahuje bibliografii
During separations in both polar and nonpolar stationary phases of gas chromatographic columns, side alkylchains of n-alkylphenols and n-alkylbenzenes become cyclized. In the aromatic-quasi-alicyclic molecules that are thereby formed, the effect of van der Waals forces is thus increased. The increase involves not only intramolecularly but also intermolecularly acting effects and becomes significantly evident when propyl and higher substituents as butyl, pentyl and hexyl constitute the side alkyl chains. As a result, boiling points considerably increase (non-linearly) in the case of n-alkylphenols and n-alkylbenzenes with total number of carbons in the molecule higher than 9. This leads to divergence in the retention characteristics of the above-mentioned compounds, which can be observed in the dependence of relative retention times on the number of carbons. Cyclization of side alkyl chains in a stationary phase is a quite new phenomenon., Pavel Straka, Petr Buryan and Jana Náhunková., and Obsahuje bibliografické odkazy