Films of aliphatic polyurethane-silica nanocomposite containing up to 27.3 mol. % of silica were obtained by the parallel synthesis of both composite components in one common process. This method permits to obtain the nanocomposite materials with the uniform distribution of nanoparticles in the polymer matrix volume. The rise of the silica concentration in the nanocomposite film was shown to lead from one hand to the progressive fall of both the Young’s modulus and yield stress and from another hand to the rise of the ultimate deformation and thermal expansion coefficient values. These effects were ascribed to the formation of the excessive free volume in the material along with the raise of silica concentration., Josif V. Gofman and Ivan V. Abalov., and Obsahuje bibliografii
This study investigates the clay mineralogy of permafrost-affected soils derived from predominantly calcareous loess-like material under the cold ultra-continental climatic conditions of Central Yakutia. These soils are named "Palevye (Pale)" following the Russian Classification, or Cryosols (WRB, 2006). Based on the data obtained, the loess-like substrate of Central Yakutia is enriched by chlorite in comparison with that of the loess-like parent material of European Russia. The clay mineralogy of the fine size fractions (<1μm) of all soil profiles is dominated by a smectitic mineral (most likely random mixed-layer illite-smectite and probably chlorite-smectite where smectite is ≥ 50 %), with subordinate chlorite and illite as well as the products of their transformation with smectite (vermiculite) layers < 50 % in the upper horizons, and finally traces of kaolinite. Pedogenesis has brought about change in the more acidic upper horizons, including a marked reduction in the expandability of the smectitic phase, possibly accounted for by the introduction of non-exchangeable hydroxy-Al into the interlamellar space and / or partial dissolving of smectitic phase, together with a relative reduction in the contents of bothillite and chlorite. Illite has been at least partially transformed to a mixed-layer illite-vermiculite (smectite), whereas chlorite has either been completely decomposed or has transformed to a mixed-layer expandable component. In one profile, the smectitic mineral appears to be absent from the upper horizon, suggesting that it may have been completely decomposed. An alternative explanation is that it has been eluted or translocated down the profile to accumulate in a Bt horizon. The distribution of clay minerals relates to the change of pH values in the profiles (acidic in the upper part, neutral - slightly alkaline in the middle, and alkaline in the basal horizons) possibly determined by seasonal migration of dissolved carbonates., Sofia N. Lessovaia, Sergey V. Goryachkin, Roman V. Desyatkin and Matrena V. Okoneshnikova., and Obsahuje bibliografické odkazy
Three variants of geophysical excitations and seven different VLBI solutions of celestial pole offsets (CPO) are used to determine period and Q-factor of Free Core Nutation (FCN). Brzeziński’s broad-band Liouville equations (Brzeziński, 1994) are numerically integrated to derive geophysical effects in nutation in time domain. Possible effect of geomagnetic jerks (GMJ) is also considered. Best-fitting values of FCN parameters are estimated by least-squares fit to observed CPO, corrected for the differences between the FCN parameters used in IAU 2000 model of nutation and newly estimated ones; MHB transfer function is used to compute these corrections. It is demonstrated that different VLBI solutions lead to FCN parameters that agree on the level of their formal uncertainties, but different models of geophysical excitations change the results more significantly. Using GMJ excitations always brings improvement of the fit between integrated and observed CPO. The obtained results show that the best fit is achieved when only GMJ excitations are used. Our conclusion is that GMJ are very probably more important for exciting FCN than the atmosphere and oceans. Empirical Sun-synchronous correction, introduced in the present IAU 2000 nutation model, cannot be explained by diurnal atmospheric tidal effects., Jan Vondrák and Cyril Ron., and Obsahuje bibliografii
Two geodynamic test transects across the Polish segment of the Western Carpathians, crossing the Orava Basin in the west (KO) and the Pieniny Klippen Belt and Magura Nappe along the Dunajec River valley in the east (DD), are presented. Multidisciplinary studies conducted along these transects incl uded gravimetric, geodetic, geologic and morphostructural investigations. Gravimetric and geodetic results appear to suggest recent subsidence of the Orava Basin, particularly intensive in the Wróblówka Graben, confirming conclusions derived from geomorphic analyses. Data ob tained for the Dunajec River transect do not show any particular differentiation among individual benchmarks, what can point to either minor uplift of the entire area (already suggested by the results of geomorphic and morphotectonic studies), minimal differences between successive slices of the Magura Nappe and the Pieniny Klippe n Belt, or both. Horizontal displacements of benchmarks, different for the KO and DD transects, towa rds the west and SW as well east and SE, respectively, can result from general uplift of the area comprised between these transects, i.e. the Gorce Mts., Monika Łój, Janusz Madej, Sławomir Porzucek and Witold Zuchiewicz., and Obsahuje bibliografické odkazy
Geodynamic processes take place in the Carpathians even nowadays. For tracing them, a research project employing gravity measurements was undertaken. Movements in the crust result in a change of mass distribution, which may be traced with the use of a gravimetric method. Two measurement profiles were designed for tracing geodynamic changes, and in the years 2004-2005 gravimetric measurements were realised. The first results of observed gravity changes are presented in the paper and are followed by preliminary conclusions on the observed changes and the assumed measurement methods., Sławomir Porzucek, Janusz Madej and Monika Łój., and Obsahuje bibliografii
In Autumn 2010 a new permanent GPS station started observati ons intended to investigate the episodic displacements o f rocks in the Książ Massif, where the Geodynamic Laboratory (LG) is situated. These investigations are being made for common interpretation with water-tubes and horizontal pendulums tiltmeters registering large (one order of magnitude greate r than the tidal effects) non-periodic geodynamic signals. The studies conducted as up to date excluded instrumental and loading effects as potential reasons of those signals. The construction of water-tube tiltmeters and their measuring principles allowed to state that the strong non-tidal signals have a geodynamic nature. To support investig ation of this problem, different analysis of the GPS data are performed in appropriate scales and applying various processing methods. The applied methods refer to selected reference GPS stations in Poland and their neighbors and are aimed at reduction of disturbance effects of geophysical origin such as tectonic activity, post-glacial rebound, anthropogenic effects, etc., Ryszard Zdunek., and Obsahuje bibliografické odkazy
Physical mass properties of various types of rocks were ascertained, and their relationships are discu ssed in this article. Basedon water permeability and mercury intrusion porosimetry methods, conductivity coefficient, porosity, and pore size distribution were determined. Furthermore, bulk and particle densities of rocks we re determined. All laboratory tests were carried out according to Czech versi on of the Technical specif ication CEN ISO/TS 17892-11:2004. The above-mentioned specification has the status of the Czech standard (ČSN, CEN). Permeability and porosity are in close relation, and it could be assumed that its relationship is linear, i.e., with increasing porosity, permeability increases as well. This relationship is influenced by other rock properties, such as the amount of open and closed pores with in the rock sample, size, and distribution of pores or mineral admixtures. From this point of view, it is necessary to study these physical properties of rocks as well, because this enables an overall analysis of rocks and its possible use for engineering constructions, Jan Šperl and Jiřina Trčková., and Obsahuje bibliografické odkazy
Permeability refers to the ability of coal to transmit gas when a pressure or concentration gradient exists across it. The permeability of coal is dependent upon factors that include effective stress, gas pressure, water content, disturbance associated with drilling and matrix swelling/shrinkage due to adsorption/desorption. A programme of laboratory tests were conducted on coal samples from the Bulli seam for evaluating the permeability and drainability of coal. Two different types of permeability apparatus were used in this study. The methods of permeability testing of coal under different triaxial conditions are discussed. Permeability testing of the Bulli seam coal with N2 is described. The laboratory test results were found to be in agreement with the calculated permeability values, Naj Aziz, Ting Ren, Jan Nemcik and Lei Zhang., and Obsahuje bibliografii
This paper presents preliminary results of the application of Persistent Scatterers Interferometry (PSI) supported with detailed field landslide mapping. The research was focused on the areas located near the towns Rabka Zdroj and Jordanow located in southern-central Poland where detailed landslide mapping campaigns were preformed in the summer of 2009. According to the field experience the average spatial density of landslide occurrence in both areas is up to 3 landslides/sq km. The application of various Synthetic Aperture Radar (SAR) interferometry techniques on the above-mentioned areas was very difficult due to the very rough topography, vegetation and forest cover, and the long season with the snow cover. Following previous successful studies on other rural areas, PSI technique was therefore applied. Field work has been carried out within the frame of a national project launched in 2008 aimed to create a detailed database of all landslides in Poland. The areas where landslide problems are extremely important are the Polish Carpathians. As in previous experiments on a sparse urbanized area we noticed that it is still possible to successfully detect a number of persistent scatterers but, the interpretation of the associated deformation is difficult. However, based on cartographic data collected during the field mapping campaign it is possible to significantly improve analysis and interpretation of PSI results., Zbigniew Perski, Tomasz Wojciechowski and Andrzej Borkowski., and Obsahuje bibliografii
a1_Phyllosilicates are classified into the following groups: 1 - Neutral 1:1 structures: the kaolinite and serpentine group. 2 - Neutral 2:1 structures: the pyrophyllite and talc group. 3 - High-charge 2:1 structures, non-expansible in polar liquids: illite and the dioctahedral and trioctahedral micas, also brittle micas. 4 - Low- to medium-charge 2:1 structures, expansible phyllosilicates in polar liquids: smectites and vermiculites. 5 - Neutral 2:1:1 structures: chlorites. 6 - Neutral to weak-char ge ribbon structures, so-called pseudophyllosilicates or hormites: palygorskite and sepiolite (fibrous crystalline clay minerals ). 7 - Amorphous clay minerals. Order-disorder states, polymorphism, polytypism, and inters tratifications of phyllosilicates are influenced by several factors: 1) a chemical micromilieu acting during the crystallization in any environment, including the space of clay pseudomorphs after original rock-forming silicates or volcanic glasses; 2) the accepted thermal energy; 3) the permeability. The composition and properties of parent rocks and minerals in the weathering crusts, the elevation, and topography of source areas and climatic conditions control the in tensity of weathering, erosion, and there sulting assemblage of phyllosilicates to be transported after erosion. The enormously high accumulation of phyllosilicates in the sedimentary lithosphere is primarily conditioned by their high up to extremely high chemical stability in water-rich environments (expressed by index of corrosion, IKO). Clastic material eroded fro m weathering crusts and transported in rivers contains overwhelming amounts of phyllosilicates inherited from original rocks. In geological literature, the newly formed phyllosilicates crystallizing in weathering crusts including soils as dominating global source of argillaceous lutite accumulations in the sedimentary lithosphere have been overestimate for a long time., a2_The dissolution of silicates in different dense rocks under conditions of weathering and the crystallization of newly formed phyllosilicates has been strongly and for long periods influenced by chemical microenvironments within each clay pseudomorph. Coarser fragments of eroded argillaceous rocks and crystals of phyllosilicates from different bedrocks and soils are very sensitive to impacts and pressure from fragments of co-transported harder and denser rocks and minerals in turbulent fluvial and similar currents. This is the most important mechanical phenomenon supporting the enormous accumulation of lutite rocks rich in phyllosilicates in the sedimentary lithosphere. The summarized new observations and interpre tations are stressed in eleven key poin ts. Erosion and water transportation of detrital material are explained in the terms of hydration, softening, swelling, physical disintegration, grinding, milling, abrasion, delamination, dispersi on, and sorting. The deposition of phyllosilicates in different fluid dynamics of streams is expressed by Re and Fr numbers and explained as unflocculated and floccu lated suspensions. Phyllosilicates an d accompanying detrital minerals in recent marine muds covering vast areas of seas and oceans as well as in lacustrine muds correspond with those transpor ted in fluvial suspensions., Jiří Konta., and Obsahuje bibliografické odkazy