Treated water from wastewater treatment plants that is increasingly used for irrigation may contain pharmaceuticals and, thus, contaminate soils. Therefore, this study focused on the impact of soil conditions on the root uptake of selected pharmaceuticals and their transformation in a chosen soil–plant system. Green pea plants were planted in 3 soils. Plants were initially irrigated with tap water. Next, they were irrigated for 20 days with a solution of either atenolol (ATE), sulfamethoxazole (SUL), carbamazepine (CAR), or all of these three compounds. The concentrations of pharmaceuticals and their metabolites [atenolol acid (AAC), N1-acetyl sulfamethoxazole (N1AS), N4-acetyl sulfamethoxazole (N4AS), carbamazepine 10,11-epoxide (EPC), 10,11-dihydrocarbamazepine (DHC), trans-10,11- dihydro-10,11-dihydroxy carbamazepine (RTC), and oxcarbazepine (OXC)] in soils and plant tissues were evaluated after harvest. The study confirmed high (CAR), moderate (ATE, AAC, SUL), and minor (N4AC) root uptake of the studied compounds by the green pea plants, nonrestricted transfer of the CAR species into the different plant tissues, and a very high efficiency in metabolizing CAR in the stems and leaves. The results showed neither a synergic nor competitive influence of the application of all compounds in the solution on their uptake by plants. The statistical analysis proved the negative relationships between the CAR sorption coefficients and the concentrations of CAR, EPC, and OXC in the roots (R = –0.916, –0.932, and –0.925, respectively) and stems (R = –0.837, –0.844, and –0.847, respectively).
The paper presents validation of a mathematical model describing the friction factor by comparing the predicted and measured results in a broad range of solid concentrations and mean particle diameters. Three different types of solids, surrounded by water as a carrier liquid, namely Canasphere, PVC, and Sand were used with solids density from 1045 to 2650 kg/m3, and in the range of solid concentrations by volume from 0.10 to 0.45. All solid particles were narrowly sized with mean particle diameters between 1.5 and 3.4 mm. It is presented that the model predicts the friction factor fairly well. The paper demonstrates that solid particle diameter plays a crucial role for the friction factor in a vertical slurry flow with coarse solid particles. The mathematical model is discussed in reference to damping of turbulence in such flows. As the friction factor is below the friction for water it is concluded that it is possible that the effect of damping of turbulence is included in the KB function, which depends on the Reynolds number.
Recent studies have shown that the presence of ice cover leads to an intensified local scour pattern in the vicinity of bridge piers. To investigate the local scour pattern in the vicinity of bridge pier under ice-covered flow condition comparing to that under open channel flow condition, it is essential to examine flow field around bridge piers under different flow conditions. In order to do so, after creation of smooth and rough ice covers, three-dimensional timeaveraged velocity components around four pairs of bridge piers were measured using an Acoustic Doppler velocimetry (ADV). The ADV measured velocity profiles describe the difference between the velocity distributions in the vicinity of bridge piers under different covered conditions. Experimental results show that the vertical velocity distribution which represents the strength of downfall velocity is the greatest under rough covered condition which leads to a greater scour depth. Besides, results show that the turbulent intensity increases with pier size regardless of flow cover, which implies that larger scour depth occurs around piers with larger diameter.
Intense collisional transport of bimodal sediment mixture in open-channel turbulent flow with water as carrying liquid is studied. The study focusses on steep inclined flows transporting solids of spherical shape and differing in either size or mass. A process of vertical sorting (segregation) of the two different solids fractions during the transport is analyzed and modelled. A segregation model is presented which is based on the kinetic theory of granular flows and builds on the Larcher-Jenkins segregation model for dry bimodal mixtures. Main modifications of the original model are the carrying medium (water instead of air) and a presence of a non-uniform distribution of sediment across the flow depth. Testing of the modified model reveals that the model is applicable to flow inclination slopes from 20 to 30 degrees approximately, making it appropriate for debris flow conditions. Changing the slope outside the specified range leads to numerical instability of the solution. A use of the bimodal mixture model is restricted to the grain size ratio 1.4 and no restriction is found for the grain mass ratio in a realistic range applicable to natural conditions. The model reveals trends in the vertical sorting under variable conditions showing that the sorting is more intense if flow is steeper and/or the difference in size or mass is bigger between the two sediment fractions in a bimodal mixture.
The paper evaluates changes in the water temperature of the Vistula River – one of the longest rivers in Europe. Mean monthly and annual water temperatures from the period 1971–2017 for 11 stations along the entire length of the river revealed the increasing trends. The mean increase in water temperature in the analysed multi-annual period was 0.31 °C dec–1. In the majority of analysed stations, the key factor determining changes in the water temperature of the river was air temperature. The observed water warming in the Vistula River should be considered an exceptionally unfavourable situation in the context of importance of water temperature for a number of processes and phenomena occurring in river ecosystems. Given the scale of changes, fast measures should be undertaken to slow down the warming.
Biocrusts are biological communities that occupy the soil surface, accumulate organic matter and mineral particles and hence strongly affect the properties of the soils they cover. Moreover, by affecting water repellency, biocrusts may cause a preferential infiltration of rainwater, with a high impact on the formation of local water pathways, especially for sand dunes. The aim of this study is to shed light on the connections between water repellency and pH, carbonate and organic matter content in two dune ecosystems with different biocrust types. For this, we used contact angle measurements, gas volumetric carbonate determination and organic matter characterization via FT-IR and TOFSIMS. In both ecosystems, moss-dominated biocrusts showed higher water repellency and higher amounts of organic matter compared to algal or cyanobacterial biocrusts. Surprisingly, the biocrusts of the two dune systems did not show differences in organic matter composition or organic coatings of the mineral grains. Biocrusts on the more acidic dunes showed a significantly higher level of water repellency as compared to higher carbonate containing dunes. We conclude that the driving factor for the increase in water repellency between cyanobacterial and moss-dominated biocrusts within one study site is the content of organic matter. However, when comparing the different study sites, we found that higher amounts of carbonate reduced biocrust water repellency.
Mosses are often overlooked; however, they are important for soil-atmosphere interfaces with regard to water exchange. This study investigated the influence of moss structural traits on maximum water storage capacities (WSCmax) and evaporation rates, and species-specific effects on water absorption and evaporation patterns in moss layers, mosssoil- interfaces and soil substrates using biocrust wetness probes. Five moss species typical for Central European temperate forests were selected: field-collected Brachythecium rutabulum, Eurhynchium striatum, Oxyrrhynchium hians and Plagiomnium undulatum; and laboratory-cultivated Amblystegium serpens and Oxyrrhynchium hians. WSCmax ranged from 14.10 g g–1 for Amblystegium serpens (Lab) to 7.31 g g–1 for Plagiomnium undulatum when immersed in water, and 11.04 g g–1 for Oxyrrhynchium hians (Lab) to 7.90 g g–1 for Oxyrrhynchium hians when sprayed, due to different morphologies depending on the growing location. Structural traits such as high leaf frequencies and small leaf areas increased WSCmax. In terms of evaporation, leaf frequency displayed a positive correlation with evaporation, while leaf area index showed a negative correlation. Moisture alterations during watering and desiccation were largely controlled by species/substrate-specific patterns. Generally, moss cover prevented desiccation of soil surfaces and was not a barrier to infiltration. To understand water’s path from moss to soil, this study made a first contribution.