This paper reports the possibilities of using FTIR spectroscopy and simultaneous thermogravimetry and differential thermal analysis for examination of the structural order of four Czech kaolinite samples (Jimlikov, Sedlec, Olomucany and Unanov deposits) and one kaolinite standard KGa-1b from Georgia deposit obtained from the Source Clays Repository of The Clay Minerals Society (USA). FTIR spectroscopy was used for the classification of the degree of structural order of kaolinite samples by empirical (IR-E) and numerical (IR-N) classification. Differential thermal analysis was used for the determination of the kaolinite disorder degree according to decomposition peak temperature obtained from DTA curves. The resulting trend of decrease in orderliness is: KGA-1b (with the best orderliness) > Jimlikov > Sedlec > Olomucany > Unanov (with the worst orderliness)., Lenka Vaculíková, Eva Plevová, Silvie Vallová and Ivan Koutník., and Obsahuje bibliografii