The thermal resistance is one of the important behaviors of the construction and thermal insulating materials. This study describes foamed material made from fluidized bed ash (FBA) in combination with natural smectite having a filler function. The foaming effect was insured by addition of metallic aluminum to the FBA/smectite mixture. Highly calcareous FBA containing calcium oxide creates during slaking processes an alkali reaction and with aluminum develops foaming agent - hydrogen. Study of thermal resistance was a part of experiments directed on heat insulating materials and article presents test results of this life gardening material. Specific attention was focused on differences between the results of chemical analyses and the crystal phases identified by X-ray diffractions. The paper presents hypothesis of chained alumina-silicates acting as bonding agent confirmed by infra-red spectroscopy and assuring together with calcium sulfates high thermal resistance even under condition of direct flame attack., Tomáš Hanzlíček and Ivana Perná., and Obsahuje bibliografii